Unit 6 · Topic 6.11 Beta

Hydrogen Fuel Cell

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A hydrogen fuel cell makes electricity from a chemical reaction, quietly, with water as its only exhaust. It is used in some cars, buses, trucks, forklifts and backup generators. The catch is that hydrogen has to be made first.

How a fuel cell works

A fuel cell drawn as three side-by-side blocks: the anode, the membrane and the cathode. Hydrogen gas enters the anode, where H2 splits into 2H+ and 2e-. Hydrogen ions cross the membrane to the cathode. Electrons flow through an outside circuit over the top, through a motor, to the cathode. Oxygen from the air enters the cathode, where O2 plus 4H+ plus 4e- form 2H2O, and water leaves the cell. A banner says hydrogen is an energy carrier that must first be made, often from natural gas or by splitting water.
Figure 1. How a hydrogen fuel cell works. LevlPrep original diagram.
  1. Hydrogen gas flows to the anode, where a catalyst (often platinum) splits each molecule into hydrogen ions (H⁺) and electrons.
  2. A membrane lets the ions through but blocks the electrons.
  3. The electrons travel through an outside circuit to the cathode. That flow is an electric current, which runs a motor or charges a small battery.
  4. At the cathode, oxygen from the air combines with the ions and electrons to form water.

Overall: hydrogen + oxygen → electricity + water + heat, or 2H₂ + O₂ → 2H₂O. Nothing burns, so there is no soot and no carbon dioxide from the cell. Many cells are stacked together to give enough power.

Hydrogen is an energy carrier

Almost no free hydrogen exists on Earth; it is locked in water and in hydrocarbons such as methane. Energy must be used to free it, so hydrogen is an energy carrier, like electricity, not an energy source.

  • From natural gas (steam reforming): most hydrogen today. It is the cheapest method but releases carbon dioxide at the plant.
  • By electrolysis: electricity splits water into hydrogen and oxygen. With electricity from wind or sunlight, the whole chain releases very little carbon dioxide, but it costs more.

Every step loses energy: making the hydrogen, compressing and moving it, and turning it back into electricity in the fuel cell.

Source to wheels. Electrolysis 70%, storage and delivery 85%, fuel cell 50%, motor 90%.

Setup: 0.70×0.85×0.50×0.90×1000.70 \times 0.85 \times 0.50 \times 0.90 \times 100

Answer: about 26.8%26.8\%. A battery car (charging 92%, battery 95%, motor 90%) delivers about 0.92×0.95×0.90×1000.92 \times 0.95 \times 0.90 \times 100≈78.7%\approx 78.7\%, roughly three times as much.

Where fuel cells fit

Because hydrogen refuels quickly and stores a lot of energy for its weight, fuel cells make the most sense where batteries would be too heavy or too slow to recharge: long-haul trucks, city buses that run all day, forklifts in warehouses, ships and backup power for hospitals and cell towers. For ordinary cars, batteries have pulled far ahead because they waste much less energy.

Fuel cell cars and battery cars

The exam has tested whether students can keep these apart.

Hydrogen fuel cell carBattery-powered car
Exhaustwater onlynone
Refuelinga few minutes at a hydrogen station30 minutes to several hours of charging
Main drawbacksfew stations; hydrogen hard to store (high pressure, flammable, low density); mostly made from natural gas; costly catalystlarge batteries need mined lithium, cobalt and nickel; long charging; battery disposal
Source-to-wheels efficiencylower (about 25 to 35%)higher (about 70 to 80%)

When asked for a fuel cell drawback, give a hydrogen problem: "making hydrogen usually uses natural gas, which releases carbon dioxide," or "hydrogen is hard to store and there are few fueling stations." Do not give long charging times.

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