Free response · Unit 3 Beta

Two amines with the same formula

Short free response · 4 points

The question

Name: ______________________   Date: ____________   Two amines with the same formula (4 points)

Data table

Two isomers of C₃H₉N

Propylamine and trimethylamine have the same molecular formula, C₃H₉N, and molar mass 59.11 g/mol. In propylamine two H atoms are bonded to the N atom; in trimethylamine the N atom is bonded to three carbon atoms and to no H.

Normal boiling points
CompoundStructureBoiling point (°C)
PropylamineCH₃CH₂CH₂NH₂48
Trimethylamine(CH₃)₃N3
  1. (a) Identify all the types of intermolecular force between molecules of liquid propylamine. [1 point]

  2. (b) Explain why propylamine has the higher boiling point. Your answer must refer to both compounds. [2 points]

  3. (c) At 25 °C, which liquid has the higher vapor pressure? Justify your answer. [1 point]